What are the most promising materials for reducing the cost of solid electrolytes

What are the most promising materials for reducing the cost of solid electrolytes

Promising Materials for Reducing the Cost of Solid Electrolytes

Solid electrolytes are crucial for the development of all-solid-state lithium-ion batteries, which promise improved safety and energy density compared to traditional liquid electrolyte batteries. However, the high cost of current solid electrolyte materials has been a significant barrier to commercialization. Recent research has focused on developing cost-effective sulfide solid electrolytes, which are promising materials for reducing costs.

1. Li7.3P2.9S10.75X0.3 (X = F, Cl, Br, I)

  • Cost Effectiveness: This material has raw material costs ranging from $27.53 to $28.13 per kilogram, significantly lower than many widely studied sulfide solid electrolytes.
  • Performance: It exhibits good electrochemical properties, including a high initial discharge capacity and satisfactory cycle stability.

2. Li7P3S7.5O3.5 (LPSO)

  • Cost Effectiveness: This electrolyte can be synthesized without expensive lithium sulfide (Li2S), resulting in raw material costs of about $14.42 per kilogram.
  • Performance: It offers low density, excellent anode compatibility, and contributes to outstanding cycling performance in all-solid-state batteries.

Challenges and Future Directions

The synthesis of sulfide solid electrolytes often relies on expensive lithium sulfide, impacting their commercial viability. New approaches that bypass this costly material can significantly reduce production costs, as seen with Li7P3S7.5O3.5 and related compounds. Continued innovation in solid electrolyte materials will be essential for making all-solid-state batteries commercially viable and safe.

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